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MATERIAL SAFETY DATA SHEET

 

CHEMICAL & POWER

MSDS #: MS-LIG-001
Issue #: 5
Date: 14-SEP-99

SECTION 1: MATERIAL IDENTIFICATION AND USE

Material Name Ammonium lignosulphonate liquids
Manufacturer Tembec Inc. - Chemical & Power Group
Address Mill Rd. Temiscaming, Que. Canada
Telephone (819) 627-4322, (819) 627-3200 in case of emergency
Supplier Tembec Inc. - Chemical & Power Group
Chemical Name Ammonium lignosulfonate
Product Codes A-002, A-005, S-002, S-006, Superbind ,. TDS
GAS Registry no. 8061-53-8
Chemical Family Spent sulfite liquors
Chemical Formula Not applicable, Polymer
Molecular Weight Not applicable, Polymer
Material use Binder, pelletizing agent, briquetting agent. macronutrients, surfactant, dust suppressant.
NFPA Ratings Health: 0, material which on exposure would offer little or no risks.

Flammability; 0, material that does not burn.

Reactivity: 0, material which is normally stable even under fire exposure conditions and which is not reactive with water.

Classification No restrictions.

SECTION 2: HAZARDOUS INGREDIENTS
Contains no hazardous ingredients

SECTION 3: PHYSICAL DATA FOR MATERIAL

Physical state Liquid
Appearance and odour Viscous brown/black liquid with light odour.
Odour threshold Not available.
Vapour Pressure Aqueous solution, like that of water.
Evaporation Rate Aqueous solution, like that of water.
% Volatile by weight 47-51, evaporation water, heating at 105° C.
Boiling point 105° C
Freezing point -5° C
Specific gravity, 25° C 1.21-1.26
pH @ 25° C 4.0-6.0 as is, (S-002: 6.5-7.5)
Solubility in water Completely at 20° C
Coefficient of oil/water distribution Not applicable, completely in water.

SECTION 4: FIRE AND EXPLOSION DATA

Flammability No, not flammable
Means of extinction Not applicable
Special procedures None
Flash point Not applicable
Upper explosion limit, % by volume Not applicable
Lower explosion limit, % by volume Not applicable
Auto ignition temperature Not applicable
Hazardous combustion products Sulfur Dioxide, Carbon Oxide (GO2, CO), Nitrogen Oxides (NOx)
Explosion data Not applicable
Rate of burning Not applicable
Explosive power Not applicable
Sensitivity to static discharge Not applicable

SECTION 5: REACTIVITY DATA

Stability Normally stable, stable below 200° C.
Hazardous Polymerization Will not occur
Incompatibility Strong oxidizing agents, concentrated acids, Nitric acid. Avoid contact with these materials.
Conditions to avoid Contact with above materials. Heating material to dryness and further to 200° C. Contact with strong base.
Hazardous Decomposition products Sulfur dioxide (SO2), carbon oxides (GO2, GO), Nitrogen Oxides (NOx). Ammonia may be released if strong alkali is applied.

SECTION 6: HEALTH HAZARD INFORMATION

Inhalation Not applicable
Skin contact Prolonged contact may cause light skin irritation in sensitive individuals.
Eye contad Avoid. Any foreign material in the eyes can cause irritation.
Ingestion None
Toxicity LD5O, Toxicological studies on lignosulfonates indicate that they are non toxic. During rat tests to determine toxicity where lignosulfonates were administered orally, no deaths were produced.
In the literature, LD50 for lignosulfonates has been reported to be 20,000 mg/kg body weight by ingestion. Materials with LD50 values of 5,000 mg/kg of body weight and greater are considered to be non toxic.
Carcinogenicity None
Mutagenicity None
Reproductive effects None
Synergistic substances None
Sensitization effects None
Irritation Practically none

SECTION 7: PREVENTATIVE MEASURES

Spill and leak procedures

Small spills, flush with water; large spills, dyke and reclaim the product.
Waste disposal

Dispose of according to local, provincial, state, and federal regulations.
Personal protective equipment

Gloves recommended for prolonged exposure. Safety glasses or goggles required to prevent eye contact. Other - work clothes should be changes on a daily basis.
Engineering controls No special precautions
Handling procedures and equipment No special precautions.
Storage No special precautions.
Special shipping information None

SECTION 8: FIRST AID MEASURES

Eye contact Flush eyes with luke warm flowing water, holding eyelids open. for at least 20 minutes. Contact physician if irritation persists.
Skin contact Wash with flowing water.
Inhalation Not applicable.
Ingestion Drink large amounts of water. Do not induce vomiting. Do not give water to unconscious person- Contact a physician if irritation persists.

 

SECTION 9: PREPARATION INFORMATION AND DATE

Prepared by: Technical staff, Chemical & Power Group
Approved by: Technical Staff
Date approved: September 13th, 1999
Sources of information: Government regulations, recognized safety practices, technical experience and knowledge of the product, and general literature.

The data and information contained herein is believed to be true to best of our knowledge at Chemical & Power Group. No warranty or representation for which Chemical & Power Group assumes legal responsibility is implied. The information refers only to the controlled product described herein and does not relate to use of the product with any other materials and processes. Chemical & Power Group encourages our customers to consider, investigate, and verify information for their uses. Chemical & Power Group assumes no responsibility for damage to properly or equipment or injury to recipient or third party persons as a result of misuse or handling of this quality product Customers are encouraged to conduct appropriate testing before use of product. The user must assure that use of information contained herein is done according to all applicable laws and regulations.

SECTION 10: ADDITIONAL INFORMATION

For many years, toxicological studies have demonstrated the non toxic, non hazardous nature of lignosulfonates. Lignosulfonates were always found to be non toxic.

Use of lignosu!fonates in animal feed and other food related applications is approved by the US FDA and Agriculture Canada. Use as a pelleting aid for animal feed, in boiler water treatment, sealing gaskets for food containers, etc. is indicated in Title 21 of the code of regulations of the US FDA. Use of lignosulfonate for pelletizing animal feed is permitted by Agriculture Canada in the Feeds Act and Feeds Regulations.

Safe use history of lignosulfonates, government regulations that permit use of lignosulfonates in animal feeds, and toxilogical studies have all demonstrated that lignosulfonates are safe, non toxic, non hazardous products.

 

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